Synthesis of Titanium and Zirconium Alkoxide by the Reaction of Titanium and Zirconium Chloride with Cyclic Ethers
نویسندگان
چکیده
منابع مشابه
Cyclic bis(β-diketonate)- and bis(β-ketoesterate)-bridged titanium and zirconium alkoxide derivatives.
Reaction of Ti(OiPr)(4) with various bis(β-diketones) and bis(β-ketoesters) (LH(2)) results in the formation of dimeric complexes [Ti(OiPr)(2)L](2), where each metal centre is coordinated by two terminal OiPr ligands and two bridging β-diketonate or β-ketoesterate groups (L). Macrocycles containing two M(OiPr)(2) moieties are thus formed. Reaction of Zr(OiPr)(4) with the same bis(β-diketones) a...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1968
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.71.3_390